采用绝热式自燃测试方法分析煤的自燃倾向

对煤的自燃倾向进行快速有效鉴别,有助于对煤的自燃倾向采取分级分类管理从而有效防治煤矿火灾,因而采用绝热式自燃测试方法对煤的自燃倾向进行准确分析很有必要。简要介绍绝热式自燃测试方法的测试原理及其仪器结构,模拟煤炭自燃的物理过程,通过采用包括反应器、气体预热铜管和跟踪温度控制方式等综合绝热措施以实现300 g煤样的自然发火实验,记录煤样从40℃上升到70℃的升温速率(或前30 h的升温速率),测试煤样的自燃特性曲线并分析曲线特征。即建立煤绝热氧化产热速率计算模型,结合实验数据计算所得的煤在绝热氧化条件下的升温速率和产热速率可鉴定煤自燃倾向性的强弱。采用绝热式自燃测试方法对不同煤的自燃倾向分析后表明,无烟煤和部分烟煤的自燃倾向较低,褐煤的自燃倾向较高,故而在煤矿开采时需特别注意褐煤的自燃倾向。     

Governance choices and policy outcomes in the Latin American and caribbean electricity sector

The paper first provides, for Latin America and the Caribbean, country-specific synthetic quantitative measures of the degree of adoption of governance reforms in the electricity sector, focusing on four key dimensions (market structure, private sector participation (PSP), regulatory autonomy and operational organization). These measures are then correlated with standard policy performance outcomes measures. The findings suggest that, the reforms, considered jointly, were statistically significantly associated with higher technical and process quality but not with social or service improvements. Considered individually, increased regulatory autonomy enjoyed the highest positive correlation with desirable outcomes, but PSP has no significant correlation with any of the outcomes. In sum, as of 2018, governance reforms, considered jointly, had still not delivered on some promised payoffs, notably in addressing energy poverty, although the sensitivity analysis suggests that, for some indicators, the relationships are stronger for larger than for smaller countries.     

带式输送机驱动滚筒的有限元分析

针对带式输送机驱动滚筒轴向受力情况,提出了正态分布模型,结合ANSYS-APDL的语言编辑能力,用ANSYS Workbench对均匀分布、一阶正弦分布和正态分布的4种模型进行有限元分析,得到驱动滚筒应力应变图及位移变形的对比情况,为日后实验验证与优化设计提供理论支持。     

镍钴电池Co-S负极材料的电化学特性研究

通过水热法制备Co-S材料,结合XRD分析其相结构,SEM和EDS分析其表面形貌及元素种类,采用充放电测试、循环伏安和交流阻抗法对其进行电化学特性研究。结果表明,该合金仅含有Co3S4、Co9S8和Co(OH)2, 结晶性良好,呈交叉生长的纳米薄片状,放电电流密度为150 mA/g时的最大放电容量为393.1mAh/g,50次循环后的容量保持率高达80.6%。当放电电流密度为1200 mA/g时,该电极的高倍率放电性能为79.3%。通过循环伏安和交流阻抗分析可知Co-S电极主要发生Co/Co(OH)2的法拉第反应,不可逆产物CoOOH的生成降低了活性物质的利用率,导致放电容量衰减。     

基于低影响开发理念的雨水控制设计计算

文中介绍了某电影文化综合体项目采用的集中雨水控制利用技术:透水性地面铺装、屋顶绿化、下凹式绿地、微生态雨水处理回用一体机。通过合理划分汇水面积,结合项目实际情况,计算给出了在限定年径流总量控制率的条件下,合理采用多种手段联合,使项目符合《绿色建筑评价标准》(GB/T 50378—2014)中的场地生态设计要求,实现了海绵城市的控制目标,也为类似工程提供了参考思路。     

含新型有机硅缓蚀剂的制备及性能研究

为了研究缓蚀剂组分及添加条件对发射药性的影响,设计并制备了一种含新型有机硅的缓蚀剂材料;采用烧蚀管法,对比石蜡+TiO2型缓蚀剂,研究了新型有机硅缓蚀剂的静态降烧蚀效果;采用密闭爆发器研究了不同缓蚀剂添加条件对高能硝胺发射药点火和燃烧性能的影响;采用14.5mm弹道枪和壁温测试装置,研究不同缓蚀剂添加条件对膛壁温度、内弹道性能和枪口烟雾的影响。结果表明,采用含新型有机硅的缓蚀剂,降烧蚀效果更为显著;随着缓蚀剂添加量的增加,压力峰值、弹丸初速也会产生小幅下降,但总体影响幅度较小;添加缓蚀剂后,射击过程膛壁峰值温度显著下降,下降幅度随着缓蚀剂添加量的增加而增加,在缓蚀剂质量分数为3%时,对身管壁温降低幅度可达17.1%,且产生的枪口烟雾量较少;在缓蚀剂质量分数为5%时,缓蚀剂添加过量,枪口产生较大烟雾。该缓蚀剂及添加条件有望应用于低烧蚀发射药配方中。     

Dynamic tensile mechanical properties and failure mode of zirconium diboride-silicon carbide ceramic composites

Dynamic indirect tension experiments were performed on zirconium diboride-silicon carbide (ZrB₂−20%SiC) ceramic. Flattened Brazilian disc specimens of ZrB₂−20%SiC were prepared to conduct dynamic tensile tests using the modified Split Hopkinson pressure bar system. The tensile experiments were completed at the range of loading rates from 7.53 to 74.71 GP s⁻¹. The tensile experimental results revealed that the zirconium diboride-silicon carbide ceramic composite is rate-sensitive in terms of the tensile strength and failure mode. The dynamic tensile strength increases linearly with the loading rate and changes from 195 MPa at 7.53 GP s⁻¹ to 654 MPa at 74.71 GP s⁻¹. Moreover, the dynamic tensile strength decreases with the increase in critical fracture time, which conforms to Tuler and Butcher's fracture criterion. In dynamic experiments, a high-speed camera was used to examine the tensile failure process, and fragments were collected to analyze the dynamic tensile failure mechanism. The tensile fracture mode of ZrB₂−20%SiC obviously showed the sensitivity of the loading rate. The fragment size of ZrB₂−20%SiC ceramic decreased but the quantity of fragments increased as the loading rate increased.     

环氧丙烷产业现状及发展趋势

简述了全球及我国环氧丙烷产业的生产及供需现状;对环氧丙烷在聚醚多元醇、丙二醇/碳酸二甲酯、丙二醇醚及其酯类等领域的应用进行了分析;并对环氧丙烷生产技术进行了比较,提出了发展建议。     

Gold Drugs with {Au(PPh3)}+ Moiety: Advantages and Medicinal Applications

Following the success of Auranofin as an anti-arthritic drug, search for novel gold drugs has afforded a large number of [L−Au(PPh₃)] complexes that exhibit notable salutary effects. Unlike Au(III)-containing species, these gold complexes with {Au(PPh₃)}⁺ moiety are stable in biological media and readily exchange L with S- and Se-containing enzymes or proteins. Such exchange leads to rapid reduction of microbial loads or induction of apoptotic cell death at malignant sites. In many cases the lipophilic {Au(PPh₃)}⁺ moiety delivers a desirable toxic L to the specific cellular target in addition to exhibiting its own beneficial activity. Further research and utilization of this synthon in drug design could lead to novel chemotherapeutics for treatment of drug-resistant pathogens and cancers.     

A system for time-fluctuating flow rate measurements in a single-blade pump circuit

Commonly used flow rate measurement systems provide an accurate and stable output value of the quasi-stationary flow rate. In some pump types as e.g. single-blade pumps significant flow rate fluctuations may occur even in steady operation points due to rotor-stator interaction. For the analysis of the time-resolved flow rate a new measurement and evaluation method is presented based on an electromagnetic flow meter. Internal averaging of the flow meter is deactivated and the raw signal is evaluated directly with a sampling rate of 3 kHz. With ensemble-averaging in combination with an impeller position detection, interfering signals acting on the time-resolved measurement signal are filtered out. Accompanying numerical simulations of the pump flow circuit are carried out with a 1D method of characteristics and validated against well-established time-resolved pressure measurements of the pump flow. Experiment and simulation show a resembling trend of pressure as well as flow rate fluctuations over the entire operation range of the pump. Thus, by the combined utilisation of measurement and simulation technique, we assure the validity of the ensemble-averaged flow rate fluctuation results. We find that the flow rate fluctuations show a consistent phase shift to the pressure fluctuations that increases towards overload. The flow rate amplitude is an order of magnitude smaller than the amplitude of the pressure fluctuations.